مروری بر نانو کامپوزیت‌های چارچوب فلز-آلی و کاربرد آن در ذخیره‌سازی گاز

نوع مقاله : مقاله مروری

نویسندگان
محمد رضا عبدی 1
ناهید سرلک 2
محمد حسین مهراراد 3
مهرناز شهرآیینی 4
1 دانشجو دکتری، گروه شیمی تجزیه، دانشکده شیمی، دانشگاه لرستان، خرم‌آباد، ایران
2 دانشیار، گروه شیمی تجزیه، دانشکده شیمی، دانشگاه لرستان، خرم‌آباد، ایران
3 معاون تجاری سازی، مدیریت پژوهش و فناوری، شرکت ملی گاز ایران، تهران، ایران
4 کارشناس ارشد کنترل طرح‌های انرژی و کربن، مدیریت انرژی و کربن، شرکت ملی گاز ایران، تهران، ایران
چکیده
این مطالعه به بررسی جامع نانوکامپوزیت‌های چارچوب فلز-آلی (MOFs) و نقش آن‌ها در ذخیره‌سازی گاز می‌پردازد. MOFها به‌دلیل دارا بودن سطح ویژه بالا، ساختار متخلخل قابل تنظیم و پایداری حرارتی-شیمیایی مطلوب، از جمله مواد نویدبخش برای ذخیره‌سازی گازهای صنعتی و انرژی‌زا (مانند هیدروژن، متان و کربن دی‌اکسید) محسوب می‌شوند. در این پژوهش، ابتدا ساختار و روش‌های سنتز این مواد (از جمله هیدروترمال، سونوشیمیایی و روش‌های مبتنی بر مایکروویو) تحلیل شده‌اند. سپس مکانیسم‌های ذخیره‌سازی گاز (جذب فیزیکی و شیمیایی) و کاربردهای آن در ذخیره‌سازی گازهای مختلف (هیدروژن، متان، کربن دی‌اکسید، گازهای نجیب و گازهای سمی) مورد بحث قرار گرفته است. علاوه بر این، تأثیر ترکیب MOFها با نانوذراتی (مانند پالادیوم و نانولوله‌های کربنی) بر افزایش ظرفیت ذخیره‌سازی، بهبود انتخاب‌پذیری و ارتقای پایداری بررسی شده است. همچنین، طبقه‌بندی MOFها شامل IRMOF ،ZIF و MIL و نقش آن‌ها در کاربردهای مختلف ارائه شده است. با این حال، چالش‌هایی نظیر هزینه تولید بالا، مسائل مقیاس‌پذیری و محدودیت‌های زیست‌محیطی، استفاده گسترده از این مواد را با دشواری مواجه کرده‌اند. در پایان، راهکارهای آینده‌نگرانه‌ای مانند به‌کارگیری روش‌های سنتز سبز، همکاری‌های بین‌رشته‌ای و پیشرفت‌های فناورانه به‌عنوان راه‌حل‌هایی برای دستیابی به فناوری‌های پایدار انرژی و حفاظت محیط‌زیست پیشنهاد شده‌اند.

کلیدواژه‌ها

موضوعات

عنوان مقاله English

A Review of Metal-Organic Framework Nanocomposites and their Application in Gas Storage

نویسندگان English

Mohammad Reza Abdi 1
Nahid Sarlak 2
Mohammad Hossein Mehrarad 3
Mehrnaz Shahraeini 4
1 Ph.D. student, Department of Analytical Chemistry, Faculty of Chemistry, Lorestan University, Khorramabad, Iran
2 Associate proffesor, Department of Analytical Chemistry, Faculty of Chemistry, Lorestan University, Khorramabad, Iran
3 Deputy of Commercialization, Research and Technology Management, National Iranian Gas Company, Tehran, Iran
4 Senior Expert in Energy and Carbon Project Control, Energy and Carbon Management, National Iranian Gas Company, Tehran, Iran
چکیده English

This article comprehensively reviews metal-organic framework (MOF) nanocomposites and their role in gas storage, which are considered to be one of the newest and most efficient materials for storing industrial and energy gases. Due to their high specific surface area, tunable porous structure, and good thermal and chemical stability, these materials are combined with nanoparticles to improve the adsorption capacity and selectivity of gases such as hydrogen, methane, and carbon dioxide. This study reviews the structure, synthesis methods (e.g., hydrothermal, sonochemical, etc.), storage mechanisms (physical and chemical adsorption), and applications in storing of hydrogen, methane, carbon dioxide, noble and toxic gases. MOFs are produced using various methods such as hydrothermal, sonochemical, and microwave, each of which has its characteristics. A table of storage capacities is provided for gases. In addition, the incorporation of MOFs with various nanoparticles increases their capacity and performance, and improves their stability and selectivity. The classification of MOFs (IRMOF, ZIF, MIL) and the role of nanoparticles (palladium, carbon nanotubes) are also reviewed. Despite the high potential, challenges such as production costs, stability, scalability, and environmental constraints remain. Suggestions for new research include green synthesis methods interdisciplinary collaborations and technological advances, promising a bright future for sustainable energy technologies and environmental protection.s.

کلیدواژه‌ها English

Metal-organic framework nanocomposites
Gas storage
Gas absorption and separation
Methane
Hydrogen
Carbon dioxide
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